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We investigate sea ice conditions during the 2020 melt season, when warm air temperature anomalies in spring led to early melt onset, an extended melt season, and the second-lowest September minimum Arctic ice extent observed. We focus on the region of the most persistent ice cover and examine melt pond depth retrieved from Ice, Cloud, and land Elevation Satellite-2 (ICESat-2) using two distinct algorithms in concert with a time series of melt pond fraction and ice concentration derived from Sentinel-2 imagery to obtain insights about the melting ice surface in three dimensions. We find the melt pond fraction derived from Sentinel-2 in the study region increased rapidly in June, with the mean melt pond fraction peaking at 16 % ± 6 % on 24 June 2020, followed by a slow decrease to 8 % ± 6 % by 3 July, and remained below 10 % for the remainder of the season through 15 September. Sea ice concentration was consistently high (>95 %) at the beginning of the melt season until 4 July, and as floes disintegrated, it decreased to a minimum of 70 % on 30 July and then became more variable, ranging from 75 % to 90 % for the remainder of the melt season. Pond depth increased steadily from a median depth of 0.40 m ± 0.17 m in early June and peaked at 0.97 m ± 0.51 m on 16 July, even as melt pond fraction had already started to decrease. Our results demonstrate that by combining high-resolution passive and active remote sensing we now have the ability to track evolving melt conditions and observe changes in the sea ice cover throughout the summer season. 

As climate warms and the transition from a perennial to a seasonal Arctic sea-ice cover is imminent, understanding melt ponding is central to understanding changes in the new Arctic. National Aeronautics and Space Administration (NASA)’s Ice, Cloud and land Elevation Satellite (ICESat-2) has the capacity to provide measurements and monitoring of the onset of melt in the Arctic and on melt progression. Yet ponds are currently not identified on the ICESat-2 standard sea-ice products, in which only a single surface is determined. The objective of this article is to introduce a mathematical algorithm that facilitates automated detection of melt ponds in the ICESat-2 Advanced Topographic Laser Altimeter System (ATLAS) data, retrieval of two surface heights, pond surface and bottom, and measurements of depth and width of melt ponds. With ATLAS, ICESat-2 carries the first spaceborne multibeam micropulse photon-counting laser altimeter system, operating at 532-nm frequency. ATLAS data are recorded as clouds of discrete photon points. The Density-Dimension Algorithm for bifurcating sea-ice reflectors (DDA-bifurcate-seaice) is an autoadaptive algorithm that solves the problem of pond detection near the 0.7-m nominal along-track spacing of ATLAS data, utilizing the radial basis function for calculation of a density field and a threshold function that automatically adapts to changes in the background, apparent surface reflectance, and some instrument effects. The DDA-bifurcate-seaice is applied to large ICESat-2 datasets from the 2019 and 2020 melt seasons in the multiyear Arctic sea-ice region. Results are evaluated by comparison with those from a manually forced algorithm. 

To enable greater control over thermal atomic layer deposition (ALD) of molybdenum disulfide (MoS 2 ), here we report studies of the reactions of molybdenum hexafluoride (MoF 6 ) and hydrogen sulfide (H 2 S) with metal oxide substrates from nucleation to few-layer films. In situ quartz crystal microbalance experiments performed at 150, 200, and 250 °C revealed temperature-dependent nucleation behavior of the MoF 6 precursor, which is attributed to variations in surface hydroxyl concentration with temperature. In situ Fourier transform infrared spectroscopy coupled with ex situ x-ray photoelectron spectroscopy (XPS) indicated the presence of molybdenum oxide and molybdenum oxyfluoride species during nucleation. Density functional theory calculations additionally support the formation of these species as well as predicted metal oxide to fluoride conversion. Residual gas analysis revealed reaction by-products, and the combined experimental and computational results provided insights into proposed nucleation surface reactions. With additional ALD cycles, Fourier transform infrared spectroscopy indicated steady film growth after ∼13 cycles at 200 °C. XPS revealed that higher deposition temperatures resulted in a higher fraction of MoS 2 within the films. Deposition temperature was found to play an important role in film morphology with amorphous films obtained at 200 °C and below, while layered films with vertical platelets were observed at 250 °C. These results provide an improved understanding of MoS 2 nucleation, which can guide surface preparation for the deposition of few-layer films and advance MoS 2 toward integration into device manufacturing. 

The topic of this paper is the airborne evaluation of ICESat-2 Advanced Topographic Laser Altimeter System (ATLAS) measurement capabilities and surface-height-determination over crevassed glacial terrain, with a focus on the geodetical accuracy of geophysical data collected from a helicopter. To obtain surface heights over crevassed and otherwise complex ice surface, ICESat-2 data are analyzed using the density-dimension algorithm for ice surfaces (DDA-ice), which yields surface heights at the nominal 0.7 m along-track spacing of ATLAS data. As the result of an ongoing surge, Negribreen, Svalbard, provided an ideal situation for the validation objectives in 2018 and 2019, because many different crevasse types and morphologically complex ice surfaces existed in close proximity. Airborne geophysical data, including laser altimeter data (profilometer data at 905 nm frequency), differential Global Positioning System (GPS), Inertial Measurement Unit (IMU) data, on-board-time-lapse imagery and photographs, were collected during two campaigns in summers of 2018 and 2019. Airborne experiment setup, geodetical correction and data processing steps are described here. To date, there is relatively little knowledge of the geodetical accuracy that can be obtained from kinematic data collection from a helicopter. Our study finds that (1) Kinematic GPS data collection with correction in post-processing yields higher accuracies than Real-Time-Kinematic (RTK) data collection. (2) Processing of only the rover data using the Natural Resources Canada Spatial Reference System Precise Point Positioning (CSRS-PPP) software is sufficiently accurate for the sub-satellite validation purpose. (3) Distances between ICESat-2 ground tracks and airborne ground tracks were generally better than 25 m, while distance between predicted and actual ICESat-2 ground track was on the order of 9 m, which allows direct comparison of ice-surface heights and spatial statistical characteristics of crevasses from the satellite and airborne measurements. (4) The Lasertech Universal Laser System (ULS), operated at up to 300 m above ground level, yields full return frequency (400 Hz) and 0.06–0.08 m on-ice along-track spacing of height measurements. (5) Cross-over differences of airborne laser altimeter data are −0.172 ± 2.564 m along straight paths, which implies a precision of approximately 2.6 m for ICESat-2 validation experiments in crevassed terrain. (6) In summary, the comparatively light-weight experiment setup of a suite of small survey equipment mounted on a Eurocopter (Helicopter AS-350) and kinematic GPS data analyzed in post-processing using CSRS-PPP leads to high accuracy repeats of the ICESat-2 tracks. The technical results (1)–(6) indicate that direct comparison of ice-surface heights and crevasse depths from the ICESat-2 and airborne laser altimeter data is warranted. Numerical evaluation of height comparisons utilizes spatial surface roughness measures. The final result of the validation is that ICESat-2 ATLAS data, analyzed with the DDA-ice, facilitate surface-height determination over crevassed terrain, in good agreement with airborne data, including spatial characteristics, such as surface roughness, crevasse spacing and depth, which are key informants on the deformation and dynamics of a glacier during surge. 

Abstract Numerous theories extending beyond the standard model of particle physics predict the existence of bosons that could constitute dark matter. In the standard halo model of galactic dark matter, the velocity distribution of the bosonic dark matter field defines a characteristic coherence time τ c . Until recently, laboratory experiments searching for bosonic dark matter fields have been in the regime where the measurement time T significantly exceeds τ c , so null results have been interpreted by assuming a bosonic field amplitude Φ 0 fixed by the average local dark matter density. Here we show that experiments operating in the T  ≪  τ c regime do not sample the full distribution of bosonic dark matter field amplitudes and therefore it is incorrect to assume a fixed value of Φ 0 when inferring constraints. Instead, in order to interpret laboratory measurements (even in the event of a discovery), it is necessary to account for the stochastic nature of such a virialized ultralight field. The constraints inferred from several previous null experiments searching for ultralight bosonic dark matter were overestimated by factors ranging from 3 to 10 depending on experimental details, model assumptions, and choice of inference framework.